Study on fractal model of activated carbon for pore formation

被引:0
作者
Junzhe Wang
Anning Zhou
Guoyang Liu
Zongxing Song
Chao Ma
Dan Wang
机构
[1] Xi’an University of Science and Technology,College of Chemistry and Chemical Engineering
[2] Shaanxi Coal Industry New Energy Technology Co.,Key Laboratory of Coal Resources Exploration and Comprehensive Utilization
[3] Ltd.,undefined
[4] Ministry of Natural,undefined
来源
Carbon Letters | 2022年 / 32卷
关键词
Fractal; Fractal dimension; Activated carbons; Pore-forming mechanism; Pore fractal growth model;
D O I
暂无
中图分类号
学科分类号
摘要
In view of the activated carbon pore-forming mechanism, the fractal hypothesis of pore interior growth was proposed by optimizing the structure of Sierpinski sponge. Based on the hypothesis and the definition of fractal dimension, the function relationship between the reaction degree, reaction step length, specific surface area and pore volume was deduced, and the pore fractal growth model of activated carbon activation process was established. Semi-coke, apple charcoal and lychee charcoal were used to prepare activated carbon. The pore size distributions of the activated carbons are in accordance with the fractal growth hypothesis. Further, the reaction degree and reaction step length can be determined by the experimental data of pore and surface structure, which verified the feasibility of the pore fractal growth model.
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页码:863 / 873
页数:10
相关论文
共 162 条
[1]  
Kyotani T(2000)Control of pore structure in carbon Carbon 38 269-286
[2]  
Alvim-Ferraz MCM(2003)Micropore size distribution of activated carbons impregnated after carbonization J Porous Mater 10 47-55
[3]  
Gaspar CMTB(2019)Surface shape and pore size change in carbon blacks isothermally oxidized in air atmosphere according to burn-off ratio Carbon Lett 29 613-623
[4]  
Lee SM(2020)Probing the active sites of site-specific nitrogen doping in metal-free graphdiyne for electrochemical oxygen reduction reactions Sci Bull 65 45-54
[5]  
Lee JH(2021)Intercalation engineering of MXenes towards highly efficient photo (electrocatalytic) hydrogen evolution reactions J Mater Chem A 9 24195-24214
[6]  
Nam G(2019)Synergistic additive-mediated CVD growth and chemical modification of 2D materials Chem Soc Rev 48 4639-4654
[7]  
Kim SH(2021)Fractal-based models study of the relative hydraulic conductivity and SWCC of bentonite by synchrotron radiation SAXS and X-ray computed tomography Fractals 29 2150208-50
[8]  
Kim J(2002)On techniques for the measurement of the mass fractal dimension of aggregates Adv Colloid Interface Sci 95 1-1433
[9]  
Roh JS(1989)An isotherm equation for adsorption on fractal surfaces of heterogeneous porous materials Langmuir 5 1431-278
[10]  
Chen X(2021)Hydration, shrinkage, pore structure and fractal dimension of silica fume modified low heat Portland cement-based materials Constr Build Mater 272 267-724