Rod-like LiV3O8/carbon composites were successfully prepared by the polymer graphitization of LiV3O8/polyaniline composites, which were synthesized through the in-situ oxidative polymerization method. The crystal phases of as-prepared samples, confirmed by X-ray diffraction, show that the interlayer spacing in LiV3O8/carbon composites is much wider than that of the pristine LiV3O8. Compared to the bare LiV3O8, the longer and smoother rod-like LiV3O8/carbon composites, investigated by scanning electron microscope and transmission electron microscope, were covered by a continuously thin layer of fluffy carbon with a thickness of approximate 20 nm. The optimal LiV3O8/carbon composite delivered a discharge capacity of 219.37 mAh g−1 in the initial cycle, and maintained a high capacity of 263.538 mAh g−1 at the 30th cycle, which was much higher than that of the pristine LiV3O8 (227.645 mAh g−1). Cyclic voltammetry measurements disclose that, after the carbon coating treatment, the phase transition of the optimal LiV3O8/carbon composite proceeds more reversibly and smoothly during charging/discharging. The improved cyclability of the optimal LiV3O8/carbon composite should be attributed to the confinement from thin carbon layer, the structural stability, the good interfacial compatibility, and the well-preserved electrode morphology after prolonged cycles.
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