Dielectric relaxation and hydrogen bond interaction study of diol-water mixtures

被引:0
作者
S. D. Chavan
B. D. Watode
P. G. Hudge
D. B. Suryawanshi
C. G. Akode
A. C. Kumbharkhane
S. C. Mehrotra
机构
[1] Swami Ramanand Teerth Marathwada University,School of Physical Sciences
[2] Dr. B A Marathwada University,Department of Computer Science & Information Technology
来源
Indian Journal of Physics | 2010年 / 84卷
关键词
Dielectric permittivity; relaxation time; time domain reflectometry; molecular interactions;
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学科分类号
摘要
Complex dielectric permittivity measurements in the frequency range 10MHz-20GHz have been carried out in diol-water mixtures over the entire concentration range using a time domain reflectometry (TDR) method at 25°C. A hydrogen bonded theory is applied to compute the dielectric constant for the mixtures. It adequately reproduces the experimental values of static dielectric constants for the diol-water mixtures. The dielectric parameters confirm that the intermolecular homogeneous and heterogeneous hydrogen bonding vary significantly with the increase in concentration of the constituents of the diol-water mixtures.
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页码:419 / 429
页数:10
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