Ceftriaxone: a novel corrosion inhibitor for mild steel in hydrochloric acid

被引:0
作者
Sudhish Kumar Shukla
M. A. Quraishi
机构
[1] Banaras Hindu University,Department of Applied Chemistry, Institute of Technology
来源
Journal of Applied Electrochemistry | 2009年 / 39卷
关键词
Mild steel; Corrosion inhibition; Weight loss; EIS; Drug;
D O I
暂无
中图分类号
学科分类号
摘要
Corrosion inhibition of mild steel in 1 N HCl by Ceftriaxone was studied by polarization resistance, Tafel polarization, EIS, and weight loss measurement. The inhibitor showed more than 90% inhibition efficiency at optimum concentration of 400 ppm. Results obtained revealed that inhibition occurs through adsorption of the drug on the metal surface without a modification of the mechanism of the corrosion process. Potentiodynamic polarization suggests that this is a mixed type of inhibitor. Electrochemical impedance spectroscopy was used to investigate the mechanism of corrosion inhibition. Thermodynamic parameters such as Ea, ΔH, ΔS, ΔG and Q were calculated to investigate the mechanism of inhibition. All the investigations suggested that the compound follows the Langmuir adsorption isotherm.
引用
收藏
页码:1517 / 1523
页数:6
相关论文
共 96 条
[1]  
Ali SA(2003)undefined Corros Sci 45 253-undefined
[2]  
Saeed MT(2002)undefined Corros Sci 44 573-undefined
[3]  
Rahman SV(2002)undefined Corrosion 58 748-undefined
[4]  
Lagrenee M(2002)undefined Br Corros J 37 155-undefined
[5]  
Mernari B(2003)undefined J Appl Electrochem 33 233-undefined
[6]  
Bouanis M(2006)undefined J Appl Electrochem 36 539-undefined
[7]  
Traisnel M(1999)undefined Corros Sci 41 789-undefined
[8]  
Bentiss F(1989)undefined Corrosion 45 1007-undefined
[9]  
Quraishi MA(1995)undefined Corrosion 51 201-undefined
[10]  
Sardar R(1963)undefined J Electrochem Soc 110 507-undefined