Metal exchange reaction of magnesium(II) octa(4-bromophenyl)tetraazaporphyrinate with copper and cobalt chlorides in dimethylformamide

被引:0
|
作者
S. V. Zvezdina
N. V. Chizhova
N. Zh. Mamardashvili
机构
[1] Russian Academy of Sciences,Krestov Institute of Solutions Chemistry
来源
Russian Journal of General Chemistry | 2014年 / 84卷
关键词
metal exchange reaction; magnesium(II); copper(II); cobalt(II) octa(4-bromophenyl)tetraazaporphyrinate; cobalt(III) octa(4-bromophenyl)tetraazaporphyrinate;
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摘要
Metal exchange reaction of magnesium(II) octa(4-bromophenyl)tetraazaporphyrinate with copper and cobalt chlorides in dimethylformamide has been studied by spectrophotometry measurements. Kinetic parameters of the metal exchange reaction have been determined. Possible stoichiometric mechanism of the reaction was proposed.
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页码:2187 / 2190
页数:3
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