Anilido-imine zinc complexes: Efficient catalysts for ring-opening polymerization of L-lactide

被引：0
|
作者：
Wei Yao
Ning Cui
Ying-zhao Xue
Tian-tian Liu
Yan Wang
机构：
[1] University of Jinan,School of Resources and Environment
来源：
Chemical Research in Chinese Universities | 2013年 / 29卷
关键词：
Anilido-imine ligand; Zinc complex; Ring-opening polymerization; Lactide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A series of anilido-imine zinc complexes ortho-C6H4(CH=NAr)(NAr)ZnEt[Ar=2,6-Me2C6H3(2a); Ar=2,6-Et2C6H3(2b)] was synthesized, characterized and used as catalysts for the ring-opening polymerization of L-lactide in the presence of benzyl alcohol. The effects of the structures of catalysts and reaction conditions on the reactivity were investigated. The polymerization of L-lactide initiated by each of these complexes was found to take place with a controlled manner.
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页码：48 / 50
页数：2
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