Syntheses, Structures, and Luminescence Properties of New Octahedral Cluster Complexes with Terminal Phenolate Ligands: [K(H2O)(CH3OH)3]2[Ph4P]2[M6Cl12(O–C6H4–F)6] (M = Nb, Ta; Ph = phenyl)

被引：0
作者：
Tao Xie
Aleksej Friedrich
Stefan Lochbrunner
Martin Köckerling
机构：
[1] University of Rostock,Solid State Inorganic Chemistry Group, Institute of Chemistry
[2] University of Rostock,Institute of Physics
来源：
Journal of Cluster Science | 2015年 / 26卷
关键词：
Niobium; Cluster; Phenolate ligand; X-ray diffraction; Luminescense;
D O I：
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学科分类号：
摘要：
The cluster compounds [K(H2O)(CH3OH)3]2[Ph4P]2[M6Cl12(para-O–C6H4–F)6] (M = Nb (1), Ta (2); Ph=phenyl) were obtained by the reaction of [Nb6Cl14(CH3OH)4]·6 CH3OH with potassium p-fluorophenolat and tetraphenylphosphonium chloride. 1 and 2 were crystallized from CH3OH and characterized by X-ray single-crystal diffraction, IR-,1H NMR-,UV–Vis- and luminescence spectroscopy.
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页码：223 / 232
页数：9
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