Reactions of N-sulfinyltrifluoromethanesulfonamide with carboxylic acids

被引:0
|
作者
B. A. Shainyan
L. L. Tolstikova
A. V. Bel’skikh
机构
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Division
来源
Russian Journal of Organic Chemistry | 2008年 / 44卷
关键词
Carboxy Group; Thionyl Chloride; Acetohydrazide; Methanesulfonamide; Trifluoromethanesulfonamide;
D O I
暂无
中图分类号
学科分类号
摘要
Phenylacetic, diphenylacetic, salicylic, and cinnamic acids reacted with N-sulfinyltrifluoromethanesulfonamide (CF3SO2NSO) to give the corresponding N-acyltrifluoromethanesulfonamides CF3SO2NHCOR (R = PhCH2, Ph2CH, o-HOC6H4, PhCH=CH). The reaction of N-sulfinyl-trifluoromethanesulfonamide with 3-hydrazinobenzoic acid occurred at the hydrazino group of the latter with conservation of the carboxy group and without elimination of SO2, and the product was 3-(2-sulfinylhydrazino)benzoic acid OSNNHC6H4CO2H.
引用
收藏
页码:1121 / 1125
页数:4
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