Ferrocene–zeolite interactions measured by inelastic neutron scattering

被引：0

作者：

E. Kemner

A.R. Overweg

U.A. Jayasooriya

S.F. Parker

I.M. de Schepper

G.J. Kearley

机构：

[1] Interfaculty Reactor Institute,

[2] Delft University of Technology,undefined

[3] Mekelweg 15,undefined

[4] 2629 JB Delft,undefined

[5] The Netherlands,undefined

[6] School of Chemical Sciences,undefined

[7] University of East Anglia,undefined

[8] Norwich NR4 7TJ,undefined

[9] UK,undefined

[10] ISIS Facility,undefined

[11] Rutherford Appleton Laboratory,undefined

[12] Chilton,undefined

[13] Didcot,undefined

[14] Oxon OX11 0QX,undefined

[15] UK,undefined

来源：

Applied Physics A | 2002年 / 74卷

关键词：

PACS: 82.75.Mj; 82.80.Gk; 68.43.Pq;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The measured inelastic neutron scattering vibrational spectrum of ferrocene, Fe(C5H5)2, in the supercages of KY zeolite is compared with that of solid ferrocene. Only small differences between these spectra are observed. It is shown that these differences are compatible with those calculated by ab initio calculations taking account only of the geometry of the ferrocene and ignoring the molecular environment. We conclude that the ferrocene–zeolite interactions are rather weak, and comparable with the intermolecular interactions in solid ferrocene.

引用

页码：s1368 / s1370