On the Theory of the Stability of Dipole Molecule Solution Interlayers in Apolar Solvents: 2. Diffuse Adsorption Layers

被引:0
|
作者
L. B. Boinovich
A. M. Emelyanenko
机构
[1] Institute of Physical Chemistry,Russian Academy of Sciences
来源
Colloid Journal | 2003年 / 65卷
关键词
Polymer; Alcohol; Hydrocarbon; Film Thickness; Adsorption Layer;
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摘要
Contribution of the image forces of dipole molecules diffusely distributed over the film thickness to disjoining pressure is considered. Relation for the dependence of this contribution on film thickness is derived. The approach to calculating the constants of dispersion interaction of solute molecules with film-confining phases is developed, and the values of these constants are calculated for a number of systems containing alcohol solutions in hydrocarbons.
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页码:678 / 683
页数:5
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