Initiation mechanisms in radical polymerization: reaction of cyanoisopropyl radicals with styrene

被引：0
|
作者：
W. Ken Busfield
Ian D. Jenkins
Phuc Van Le
机构：
[1] Griffith University,Faculty of Science and Technology
[2] Nathan,undefined
来源：
Polymer Bulletin | 1997年 / 38卷
关键词：
Styrene; AIBN; Styrene Oxide; Radical Trapping; Isoindol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of styree with AIBN in the presence of the aminoxyl scavenger 1,1,3,3-tetramethyl-1,3-dihydro-1H-isoindol-2-yloxyl is reported. By keeping the concentration of the aminoxyl radicals very low, the addition of cyanoisopropyl radicals to styrene becomes competitive ith radical trapping. Traces of adventitious oxygen give rise to some unusual reactions and products.
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页码：149 / 155
页数：6
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