Molecular structure of AlH3[N(CH2CH2)3CH]2

被引：0
作者：
C. Jeff Harlan
Simon G. Bott
Andrew R. Barron
机构：
[1] Rice University,Department of Chemistry
[2] University of Houston,Department of Chemistry
来源：
Journal of Chemical Crystallography | 1998年 / 28卷
关键词：
Crystal structure; aluminum; hydride; complex; quinuclidine;
D O I：
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学科分类号：
摘要：
Reaction of AlH3[N(CH2CH2)3CH] with hexamethyltrisiloxane, (OSiMe2)3, gives rise to the bis-quinuclidine complex AlH3[N(CH2CH2)3CH]2, which has been characterized by 1H and 13C NMR spectroscopy and X-ray crystallography. The molecular structure of AlH3[N(CH2CH2)3CH]2 consists of a trigonal bipyramidal aluminum with axial coordination of the quinuclidine ligands. Crystal data: orthorhombic, space group Pbcn, a = 10.6895(9), b = 12.266(1), c = 12.3794(9) Å, V = 1623.2(2) Å3, and Z = 4.
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页码：649 / 651
页数：2
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