Study of the influence of isomerism on the curing properties of the epoxy system DGEBA (n=0)/1,2 DCH by DEA and MDSC

被引:0
作者
L. Núńez-Regueira
S. Gómez-Barreiro
C. A. Gracia-Fernández
机构
[1] Research Group TERBIPROMAT,
[2] Departamento Física Aplicada,undefined
[3] Universidade de Santiago,undefined
[4] Research Group TERBIPROMAT,undefined
[5] Departamento Física Aplicada,undefined
[6] Universidade de Santiago,undefined
[7] Research Group TERBIPROMAT,undefined
[8] Departamento Física Aplicada,undefined
[9] Universidade de Santiago,undefined
来源
Journal of Thermal Analysis and Calorimetry | 2005年 / 82卷
关键词
MDSC; epoxy; DEA; isomer;
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摘要
Modulated differential scanning calorimetry (MDSC) and dielectric analysis (DEA) have been used to characterize the cure process of the system diglycidyl ether of bisphenol A (DGEBA(n=0)/1,2 diaminocyclohexane (1,2 DCH). The trans isomer and a mixture cis/trans(30-70% respectively) of 1,2 DCH were used to find their different behaviour. The study allowed to check the influence of the cisisomer on the thermoset curing process. Gelation times were obtained through the equation proposed by Johari and vitrification times from the point of inflection of the complex calorific capacity modulus.
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页码:797 / 801
页数:4
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