Tuning the Properties of Refractory Carbide Nanopowders

被引:8
作者
Blagoveshchenskiy Y.V. [1 ]
Isaeva N.V. [1 ]
Sinaiskiy M.A. [1 ]
Ankudinov A.B. [1 ]
Zelensky V.A. [1 ]
机构
[1] Institute of Metallurgy and Materials Sciences IMET, Russian Academy of Sciences, Moscow
关键词
high-energy ball milling; nanopowders; plasma chemical synthesis; properties; transition metal carbide;
D O I
10.1134/S2075113318050039
中图分类号
学科分类号
摘要
Two methods for transition metal carbide nanopowder production such as plasma chemical synthesis and high-energy ball milling are considered. The control of the chemical, phase, and dispersed composition of carbides produced from oxide and halogenide raw materials is studied by an electric arc plasma plant with a power of 20 kW. A study of the grinding time effect of micron-sized carbide powders on a Retsch PM-400 mill tool in hard-alloy containers is carried out to obtain nanosized powders, as well as to determine fractional composition and particle shapes. It is shown that powders obtained by plasma chemical synthesis have a grain size of 20–80 nm and are subjected to a spheroidized or equiaxed shape. The process allows one to tune the phase composition and the content of common and free carbon. Polydispersed carbide powders with a specific surface area of 3–25 m2/g and predominately bimodal particle size distribution in a range from less than 0.1 μm to dozens of microns are thus obtained by high-energy ball milling. © 2018, Pleiades Publishing, Ltd.
引用
收藏
页码:924 / 929
页数:5
相关论文
共 13 条
[1]  
Storms E.K., The Refractory Carbides, (1967)
[2]  
Tsvetkov Y.V., Panfilov S.A., Nizkotemperaturnaya plazma v protsessakh vosstanovleniya (Low-Temperature Plasma in Reduction Processes), (1980)
[3]  
Alekseev N.V., Blagoveshchenskii Y.V., Zviadadze G.N., Tagirov I.K., Production of fine niobium and tantalum carbide powders, Sov. Powder Metall. Met. Ceram., 19, 8, pp. 517-520, (1980)
[4]  
Isaeva N.V., Blagoveshchenskii Y.V., Blagoveshchenskay, a N.V, Mel’nik, Yu.I., Samokhin, A.V., Alekseev, N.V., and Astashov, A.G., Preparation of nanopowders of carbides and hard-alloy mixtures applying low-temperature plasma, Russ. J. Non-Ferrous Met., 55, 6, pp. 585-591, (2014)
[5]  
Ryu T., Sohn H.Y., Hwang K.S., Fang Z.Z., Plasma synthesis of tungsten carbide and cobalt nanocomposite powder, J. Alloys Compd., 481, pp. 274-277, (2009)
[6]  
Avvakumov E.G., Mekhanicheskie metody aktivatsii khimicheskikh protsessov (Mechanical Activation of Chemical Processes), (1986)
[7]  
Boldyrev V.V., Mechanochemistry and mechanical activation of solids, Russ. Chem. Rev., 75, 3, pp. 177-189, (2006)
[8]  
Yang M., Guo Z., Xiong J., Liu F., Qi K., Microstructural changes of (Ti,W)C solid solution induced by ball milling, Int. J. Refract. Met. Hard Mater., 66, pp. 83-87, (2017)
[9]  
Kurlov A.S., Gusev A.I., Effect of nonstoichiometry of NbCy and TaCy powders on their high-energy ball milling, Int. J. Refract. Met. Hard Mater., 46, pp. 125-136, (2014)
[10]  
Seo M., Kang S., Kim Y., Ryu S.-S., Preparation of WC nanoparticles by twice ball milling, Int. J. Refract. Met. Hard Mater., 41, pp. 191-197, (2013)