High temperature oxidation resistance of Ni-(5∼13)Co-(10∼16)Cr-(5∼9)W-5Al-(1∼1.5)Ti-(3∼6)Ta alloys

The oxidation behavior of Ni-based superalloys was examined by cyclic oxidation tests at 850 and 1000 °C. The present study focused on the investigation of two newly developed and three commercial alloys (GTD-111, IN738LC, and CM247LC). The oxidation resistance of the superalloys were evaluated by the oxidation rate constants and the mass gains. The oxidation scales mainly consisted of outer Cr2O3 and inner Al2O3 layers at both temperatures, as well as oxides of minor elements such as TiO2, NiCr2O4, CrTaO4, HfO2, and TaO. The oxidation resistance of the alloys containing larger amounts of Al, W, and Ta and lower Mo and Ti concentrations was higher than those of the other alloys. The ranking of oxidation resistance for the alloys corresponded to the statistical prediction drawn from a response surface analysis. Furthermore, these alloys contained more Ta oxides, such as CrTaO4 and TaO, suggesting that Ta oxides had an active role in improving the oxidation resistance.