Synthesis and crystal structure of a new tetradecker complex: Tetra(μ4-N,N′-Ethylen-bis(3-Methoxysalicylideneamine)-bis(μ2-perchlorato-O,O′)-tetranickel(II)-tripotassium perchlorate

被引：0
作者：
D. Zhang
Z. Zhao
机构：
[1] Shandong University of Technology,College of Chemical Engineering
来源：
Russian Journal of Coordination Chemistry | 2011年 / 37卷
关键词：
Phth Alocyanine; Schiff Base Ligand; Nather; Phenolic Oxygen Atom; Double Decker;
D O I：
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学科分类号：
摘要：
The title tetradecker complex C72H72Cl3K3N8Ni4O28 has been synthesized and structurally characterized. The four NiL (L = N, N-ethylene-bis(3-methoxysalicylideneiminate) segments were linked into a discrete tetradecker structure by three K+ cation coordinated to the phenolic oxygen atoms of the neighboring NiL units and the oxygen atom of the ClO4− anions acting as bridges. The two bicephalous K+ cations are nine-coordinated, while the middle one is involved in a distorted bipentagonal pyramid. For the Ni2+ ion, it is involved in a square planar coordination sphere formed by a N2O2 unit from the Schiff base ligand.
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页码：931 / 934
页数：3
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