Elementary Act of Dissociative Adsorption of Two–Atom Molecules on a Solid Surface in a Polar Solvent

被引：0

作者：

E. D. German

A. M. Kuznetsov

I. Efremenko

机构：

[1] Technion,Faculty of Engineering Chemistry

[2] Russian Academy of Sciences,Frumkin Institute of Electrochemistry

来源：

Russian Journal of Electrochemistry | 2003年 / 39卷

关键词：

Physical Chemistry; Potential Energy; Solid Surface; Polar Solvent; Solvent Structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A model is suggested for the description of an elementary act of dissociative adsorption of molecules of the X2 type at a solid surface in a polar solvent. Within this model, the potential energy of interaction between the molecule and the surface and the intramolecular energy of X2 are approximated by Morse functions. The model accounts for the reorganization of the substrate and polar solvent structures. The model is compared with other approximations.

引用

页码：61 / 65

页数：4

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