Synthesis, electrochemical properties and electro-oxidative polymerization of copper(II) and nickel(II) complexes with N′-benzoylthiourea ligands containing pyrrole groups

被引：0

作者：

José Losada

Isabel del Peso

Lothar Beyer

机构：

[1] Universidad Politécnica Madrid,Departamento Ingeniería Química Industrial, ETS de Ingenieros Industriales

[2] Universität Leipzig,Fakultät für Chemie und Mineralogie

[3] D,undefined

来源：

Transition Metal Chemistry | 2000年 / 25卷

关键词：

Copper; Nickel; Cyclic Voltammetry; Pyrrole; Glassy Carbon;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The synthesis of four N′-benzoylthioureas containing pyrrole groups are described. The electrochemical behaviour of their copper(II) and nickel(II) complexes has been investigated in aprotic solvents by coulometry and by cyclic voltammetry which indicates that the electrochemical oxidation of copper complexes leads to the formation of CuII-benzylureate complexes. The oxidative polymerization of nickel complexes on platinum and a glassy carbon electrode, has been carried out in MeCN.

引用

页码：112 / 117

页数：5

共 41 条

[1] Mühl P.(1986)undefined Z. Chem. 268 81-undefined
[2] Hoyer K.(1986)undefined Z. Analyt. Chem. 325 621-undefined
[3] Dietze F.(1981)undefined Z. Chem. 21 81-undefined
[4] Beyer L.(1992)undefined Nachr. Chem. Techn. Lab. 40 682-undefined
[5] König K.H.(1991)undefined J. Prakt. Chem. 333 537-undefined
[6] Pletsch H.J.(1994)undefined Polyhedron. 13 1363-undefined
[7] Schuster M.(1994)undefined Polyhedron. 13 3277-undefined
[8] Beyer L.(1996)undefined Fresenius J. Analyt. Chem. 356 263-undefined
[9] Hoyer H.(1996)undefined Coord. Chem. Rev. 147 339-undefined
[10] Liebscher J.(1967)undefined Spectrochim. Acta. 23A 1037-undefined

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