Bifunctional Nanoscopic Catalysts for the One-Pot Synthesis of (±)-Menthol from Citral

被引：0
|
作者：
Alina Negoi
Katharina Teinz
Erhard Kemnitz
Stefan Wuttke
Vasile I. Parvulescu
Simona M. Coman
机构：
[1] University of Bucharest,Department of Organic Chemistry, Biochemistry and Catalysis, Faculty of Chemistry
[2] Institut fur Chemie,Department of Chemistry
[3] Humboldt-Universitat zu Berlin,undefined
[4] University of Munich (LMU),undefined
来源：
Topics in Catalysis | 2012年 / 55卷
关键词：
Noble metals; Doped nanoscopic fluorides; Sol–gel synthesis; Beta zeolite; Impregnation; Citral; Menthol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Active and selective bifunctional Me(Ir, Pd)/beta zeolite and doped nanoscopic hydroxylated fluorides (0.1 % Pd (or Pt)/AlF3) catalysts were developed for the one-pot synthesis of menthols from citral. In the case of fluoride catalysts, the strong electron-withdrawing effect of the dominating fluoride environment depletes the metal surface from electrons and hence, favours the hydrogenation of the C=C bond to citronellal on both Pd and Pt-based catalysts.
引用
收藏
页码：680 / 687
页数：7
相关论文
共 40 条
  • [31] Catalytic production of γ-valerolactone, a biofuel precursor, from furfural in one-pot: Synergistic effect between Zr and Sn
    Garcia, Adrian
    Sanchez-Tovar, Rita
    Miguel, Pablo J.
    Montejano-Nares, Elena
    Ivars-Barcelo, Francisco
    Cecilia, Juan Antonio
    Torres-Olea, Benjamin
    Solsona, Benjamin
    FUEL, 2023, 352
  • [32] Trapping carbamates of ?-Amino acids: One-Pot and catalyst-free synthesis of 5-Aryl-2-Oxazolidinonyl derivatives
    Bresciani, Giulio
    Zacchini, Stefano
    Famlonga, Luca
    Pampaloni, Guido
    Marchetti, Fabio
    JOURNAL OF CO2 UTILIZATION, 2021, 47
  • [33] Facile one-pot synthesis of plasmonic gold nanoparticles decorated porphyrin-metal organic framework for photocatalytic hydrogen evolution
    Pena, Edward
    Becerra, Jorge
    Gopalakrishnan, Vishnu Nair
    Do, Trong-On
    MOLECULAR CATALYSIS, 2023, 548
  • [34] HZ-ZrP Catalysts with Adjustable Ratio of Bronsted and Lewis Acids for the One-Pot Value-Added Conversion of Biomass-Derived Furfural
    Ye, Lei
    Han, Yiwen
    Bai, Hui
    Lu, Xuebin
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (19) : 7403 - 7413
  • [35] Effective catalytic steam reforming of naphthalene over Ni-modified ZSM-5 via one-pot hydrothermal synthesis
    Liu, Yawen
    Liu, Lina
    Diao, Xungang
    Liang, Jie
    Wu, Chunfei
    Sun, Yifei
    WASTE MANAGEMENT, 2022, 147 : 1 - 9
  • [36] The Simpler the Better: One-Pot Production of γ-Valerolactone from Biomass Conversion through All-In-One Sc(OTf)3 Catalyzed Cascade Reaction
    Hao, Rui
    Liu, Tianwei
    He, Jianghua
    Zhang, Yuetao
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 13 (09)
  • [37] A novel and clean technique for the one-pot production of green chemical γ-valerolactone from furfural using bifunctional H3PW12O4/UiO-66 catalyst: Pervaporation membrane reactor
    Mutlu, Bade
    Unal, Buse
    Unlu, Derya
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2024, 12 (03):
  • [38] Two-carbons homologation of methyl ketones examplified for the synthesis of citral from 6-methyl-5-hepten-2-one
    Valla, A
    Cartier, D
    Laurent, A
    Valla, B
    Labia, R
    Potier, P
    SYNTHETIC COMMUNICATIONS, 2003, 33 (07) : 1195 - 1201
  • [39] Understanding the role of Al/Zr ratio in Zr-Al-Beta zeolite: Towards the one-pot production of GVL from glucose
    Paniagua, Marta
    Morales, Gabriel
    Melero, Juan A.
    Iglesias, Jose
    Lopez-Aguado, Clara
    Vidal, Nora
    Mariscal, Rafael
    Lopez-Granados, Manuel
    Martinez-Salazar, Irene
    CATALYSIS TODAY, 2021, 367 : 228 - 238
  • [40] One-pot synthesis of Cu-SAPO-34 catalyst using waste mother liquid and its application in the selective catalytic reduction of NO with NH3
    Bing, Liancheng
    Wang, Guangjian
    Yi, Kaifeng
    Tian, Aixiu
    Wang, Fang
    Wu, Chunze
    CATALYSIS TODAY, 2018, 316 : 37 - 42
1234