Role of the Surface Acid–Base Properties of Silver Catalysts in the Partial Oxidation of Ethylene Glycol

被引：0
作者：
G. A. Voronova
O. V. Vodyankina
V. N. Belousova
E. V. Bezrukov
L. N. Kurina
机构：
[1] Tomsk Polytechnical Institute,Siberian Division, Russian Academy of Sciences
[2] Tomsk State University,undefined
[3] Institute of Petrochemistry,undefined
[4] Tomsk State University,undefined
来源：
Kinetics and Catalysis | 2003年 / 44卷
关键词：
Oxidation; Ethylene; Physical Chemistry; Ethylene Glycol; Catalytic Activity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The acid–base properties of a bulk silver catalyst and silver catalysts supported on various carriers for the partial oxidation of ethylene glycol were studied. A relationship between the catalytic activity and the concentration of surface acid sites in the catalysts was found. A mechanism was proposed for the participation of Lewis acid sites in the reaction of partial ethylene glycol oxidation to glyoxal.
引用
收藏
页码：652 / 656
页数：4
相关论文
共 36 条
[1]  
Pestryakov A.N.(1986)undefined Zh. Fiz. Khim. 60 2081-undefined
[2]  
Davydov A.A.(1987)undefined Zh. Fiz. Khim. 61 2381-undefined
[3]  
Kurina L.N.(1984)undefined Zh. Prikl. Khim. 4 921-undefined
[4]  
Pestryakov A.N.(1984)undefined Dokl. Akad. Nauk BSSR 28 733-undefined
[5]  
Davydov A.A.(1988)undefined Zh. Fiz. Khim. 62 1813-undefined
[6]  
Kurina L.N.(2001)undefined Zh. Fiz. Khim. 75 234-undefined
[7]  
Belousova V.N.(1997)undefined Khim. Prom-st. 12 802-undefined
[8]  
Kuznetsova O.G.(1995)undefined Zavod. Lab. 8 12-undefined
[9]  
Kurina L.N.(1995)undefined Kinet. Katal. 6 889-undefined
[10]  
Matveichuk S.V.(1989)undefined J. Am. Chem. Soc. 111 3570-undefined
1234