Molecular and crystal structure of bis{1,4-bis(1,2,4-triazol-1-yl)butane}dibromocadmium(II)

被引:0
|
作者
L. Shen
机构
[1] Hangzhou Normal University,Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, College of Material Chemistry and Chemical Engineering
来源
Russian Journal of Coordination Chemistry | 2010年 / 36卷
关键词
Butane; Coordination Chemistry; Coordination Polymer; CdBr; Dicyana Mide;
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学科分类号
摘要
The structure of [Cd(Btb)2Br2] (I) (Btb = 1,4-bis(triazol-1-yl)butane) exhibits a two-dimensional (4,4) network through Btb-bridge in which the Cd(II) atom is in a distorted octahedral environment formed by four nitrogen atoms of the triazoles and two trans-Br atoms. The crystals are monoclinic, space group P21/n with a = 7.6778(6), b = 18.2237(8), c = 8.7655(5) Å, β = 113.4534(19)°. The Btb ligand demonstrates the completely anti conformation.
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页码:117 / 119
页数:2
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