Interpolymer complexes of copolymers of vinyl ether of diethylene glycol with poly(acrylic acid)

被引：0
|
作者：
Grigoriy A. Mun
Zauresh S. Nurkeeva
Vitaliy V. Khutoryanskiy
Aibek D. Sergaziyev
机构：
[1] Kazakh State National University Department of Macromolecular Chemistry,
[2] Karasai Batyra Str. 95 480012 Almaty,undefined
[3] Kazakhstan e-mail: khutor@nursat.kz,undefined
来源：
Colloid and Polymer Science | 2002年 / 280卷
关键词：
Keywords Interpolymer complexes Hydrophobic–hydrophilic balance; Critical pH; Stability;
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摘要：
 The complex formation reactions of poly(vinyl ether of diethylene glycol) as well as vinyl ether of diethylene glycol–vinyl butyl ether copolymers with poly(acrylic acid) have been studied in aqueous and alcohol solutions. The formation of interpolymer complexes which were stabilized by hydrogen bonds was shown. The effects of molecular weight of poly(acrylic acid) and the nature of the nonionic polymer on the composition and stability of interpolymer complexes were clarified. The critical pH values of complexation were determined for different systems with various molecular weights and hydrophobic–hydrophilic balances. The stability of the interpolymer complexes formed in aqueous and alcohol solutions with respect to dimethylformamide addition was evaluated. The role of hydrophobic interactions and the presence of active groups on stability of the interpolymer complexes is discussed.
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页码：282 / 289
页数：7
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