Crystal and molecular structure of 13-diethanolamino-deacetyllaurenobiolide. Macrocycle conformation in linear germacrolides

被引:0
作者
B. Tashkhodzhaev
I. D. Sham’yanov
M. B. Izbosarov
M. Yu. Antipin
机构
[1] Academy of Sciences of the Republic of Uzbekistan,S. Yu. Yunusov Institute of the Chemistry of Plant Substances
[2] Tashkent Pharmaceutical Institute,Institute of Element
[3] Russian Academy of Sciences,organic Compounds
来源
Chemistry of Natural Compounds | 2004年 / 40卷
关键词
sesquiterpene lactone; germacranolide; 13-diethanolamino-deacetyllaurenobiolide; x-ray structure analysis;
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学科分类号
摘要
An x-ray structure analysis of the 13-diethanolamino derivative of deacetyllaurenobiolide, a germacrane sesquiterpene lactone, was performed. The germacrane macrocycle has the chairchair conformation with the 15D5,1D14 configuration. The conformation of the macrocycle in linear germacrolides was analyzed.
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页码:552 / 556
页数:4
相关论文
共 49 条
[1]  
Watson W. H.(1986)undefined J. Org. Chem. 51 2521-undefined
[2]  
Kashyap R. P.(1983)undefined Phytochemistry 22 1637-undefined
[3]  
Bohlmann F.(1980)undefined Phytochemistry 19 115-undefined
[4]  
Jakupovic J.(1982)undefined Phytochemistry 21 1349-undefined
[5]  
Schuster A.(1983)undefined Phytochemistry 22 1623-undefined
[6]  
Bohlmann F.(1992)undefined J. Crystallogr. Spectrosc. Res. 22 461-undefined
[7]  
Zdero S.(1984)undefined Phytochemistry 23 1971-undefined
[8]  
King R. M.(1983)undefined J. Chem. Soc. Perkin Trans. I 2027-undefined
[9]  
Robinson H.(1999)undefined Phytochemistry 51 529-undefined
[10]  
Bohlmann F.(1986)undefined Gazz. Chim. Ital. 116 57-undefined