Synthesis and Complexation Behavior Studies of Novel Bis-crown Ethers

被引：0
作者：
Zhi Bin Huang
Seung Hyun Chang
机构：
[1] Daegu University,Department of Chemistry
来源：
Journal of inclusion phenomena and macrocyclic chemistry | 2006年 / 55卷
关键词：
aminobenzo-crown ether; aminomethyl-crown ether; aza-crown ether; bis-crown ether; Michael addition;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The novel unique structures of bis-crown ethers were successfully synthesized from tri (propylene glycol) di-acrylate with amino- and aza-crown ethers through Michael addition. The crown ethers contained the primary and the secondary amine group such as 2-aminomethyl crown ethers, 4-aminobenzo crown ethers and 1-aza crown ethers. The newly synthesized bis-crown ethers were characterized by elemental analyses, IR, 1H NMR, 13C NMR, mass spectrum, respectively. The newly synthesized host compounds of bis-crown ethers showed complex ability with various sizes of alkali metal cations such as Na+, K+, Rb+ and Cs+. The complexation behavior was examined by 1H NMR spectroscopy and UV spectrometry.
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页码：341 / 346
页数：5
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