Global and local interactions in the structure of crystalline 7-(diethylamino)-2-(2-oxo-2H-chromen-3-yl)chromenium perchlorate

被引:0
|
作者
Beata Zadykowicz
Michał Wera
Edward V. Sanin
Alexander I. Novikov
Alexander D. Roshal
Artur Sikorski
Piotr Storoniak
Jerzy Błażejowski
机构
[1] University of Gdańsk,Faculty of Chemistry
[2] V. N. Karazin National University,Institute of Chemistry
来源
Structural Chemistry | 2016年 / 27卷
关键词
2-(Coumarinyl)chromenium salt; Crystal engineering and structure; Thermodynamics and features of global and local interactions; Spectral properties;
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学科分类号
摘要
Computational methods were used to calculate the crystal lattice energy reflecting global interactions, predominantly long-range electrostatic interactions between ions, as well as the energy of selected specific local C–H···O, C–H···π and π···π interactions found in synthesized 7-(diethylamino)-2-(2-oxo-2H-chromen-3-yl)chromenium perchlorate, the structure of which was determined by X-ray crystallography. Local interactions occurring between specific sites of molecules, amounting to a few tens of kJ mol−1, most likely account for the mutual arrangement of molecular ions, whereas global ones, exceeding half-a-thousand kJ mol−1, are responsible for the thermodynamic stability of the compound investigated in the crystalline solid phase, whose potential applications are briefly outlined.
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页码:637 / 649
页数:12
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