Poly[tetraaquatriglutaratodicerium(III) decahydrate], a novel luminescent metal-organic framework possessing hydrophilic hexagonal channels

被引：0
作者：
REMYA M NAIR
M R SUDARSANAKUMAR
S SUMA
M R PRATHAPACHANDRA KURUP
P K SUDHADEVI ANTHARJANAM
机构：
[1] Mahatma Gandhi College,Department of Chemistry
[2] VTM NSS College,Department of Chemistry
[3] S N College,Department of Applied Chemistry
[4] Cochin University of Science and Technology,undefined
[5] XRD Lab,undefined
[6] SAIF,undefined
[7] IIT-Madras,undefined
来源：
Journal of Chemical Sciences | 2016年 / 128卷
关键词：
Metal-organic framework; gel method; 2D complex; porous architecture; hydrophilic channels; luminescence.;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel 2D metal–organic framework poly[tetraaquatriglutaratodicerium(III) decahydrate] with an open framework structure has been successfully grown by single gel diffusion technique. Sodium metasilicate was used for gel preparation. The structure was determined by single crystal X-ray diffraction. The compound crystallizes in orthorhombic space group Pnma and possesses a structure consisting of [CeO10] polyhedra and H2O molecules with hydrophilic hexagonal channels. The crystals were further characterized by elemental analysis, FT-IR and UV-Visible spectroscopy, powder X-ray diffraction and thermogravimetry. The luminescent property and magnetic susceptibility of the complex were also investigated.
引用
收藏
页码：1385 / 1393
页数：8
相关论文
共 134 条
[21]  
Gomez-Lor B(2016)undefined Inorg. Chem. Commun. 63 81-undefined
[22]  
Gutierrez-Puebla E(2016)undefined J. Mol. Struct. 1105 316-undefined
[23]  
Iglesias M(2002)undefined Acta. Cryst. 58B 389-undefined
[24]  
Monge MA(2010)undefined Bull. Kor. Chem. Soc. 31 1058-undefined
[25]  
Prosperpio DM(2005)undefined J. Am. Chem. Soc. 127 17998-undefined
[26]  
Snejko N(2009)undefined Pure Appl. Chem. 81 2235-undefined
[27]  
Perles J(2014)undefined J. Chem. Sci. 126 127-undefined
[28]  
Iglesias M(2011)undefined Inorg. Chim. Acta 365 269-undefined
[29]  
Ruiz-Valero C(2006)undefined Inorg. Chim. Acta 359 4130-undefined
[30]  
Snejko N(2006)undefined Glass Ceram. 66 7-undefined
12345678910