Structure and Reactivity of Gas‐Phase Molybdenum Oxide Cluster Ions

被引：0

作者：

V. B. Goncharov

E. F. Fialko

机构：

[1] Russian Academy of Sciences,Boreskov Institute of Catalysis, Siberian Branch

来源：

Journal of Structural Chemistry | 2002年 / 43卷

关键词：

Oxide; Oxygen; Inorganic Chemistry; Carbon Monoxide; Molybdenum;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Combining the ion cyclotron resonance method and a Knudsen effusion source, we obtained a series of MoxOy+ (x = 1 – 5, y = 1 – 15) molybdenum oxide cluster ions. We studied the dependence of the concentrations of these ions on the trapping time and their reactions with carbon monoxide. It is shown that MoxOy+ ions with x > 3 contain a cyclic Mo3O9 fragment in their structure. The oxygen bond energies in MoxOy+ ionic clusters are estimated.

引用

页码：777 / 782

页数：5

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