The Internal Pressure and Cohesive Energy Density of Liquid Metallic Elements

被引:0
作者
Yizhak Marcus
机构
[1] The Hebrew University of Jerusalem,Institute of Chemistry
来源
International Journal of Thermophysics | 2017年 / 38卷
关键词
Cohesive energy density; Internal pressure; Liquid metals;
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摘要
The internal pressures, Pint\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$P_{\mathrm{int}}$$\end{document}, of practically all the liquid metallic elements in the periodic table up to plutonium (except highly radioactive ones) at their melting points were calculated from data in the literature. They are compared with the respective cohesive energy densities, ced, obtained from the literature data too. The ratios Pint/ced\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$P_{\mathrm{int}}{/}ced$$\end{document} for various liquids are ranked as follows: molten salts < polar/hydrogen-bonded molecular solvents ∼\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\sim $$\end{document} liquid metals < room temperature ionic liquids < nonpolar molecular solvents, and the reverse of this list reflects the relative strengths of the mutual interactions of the particles constituting these liquids.
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  • [1] Frank HS(1943)undefined J. Chem. Phys. 13 493-undefined
  • [2] Paskin A(1967)undefined Adv. Phys. 16 223-undefined
  • [3] Blairs S(1993)undefined Acustica 79 64-undefined
  • [4] Abbasi MH(2007)undefined Phys. B 387 344-undefined
  • [5] Singh RN(2009)undefined Metall. Mater. Trans. B 40 959-undefined
  • [6] Arafin S(2013)undefined AIP Conf. Proc. 1536 791-undefined
  • [7] George AK(2008)undefined Mater. Sci. Eng. A 495 19-undefined
  • [8] Iida T(1986)undefined Rep. Prog. Phys. 49 341-undefined
  • [9] Guthrie R(2011)undefined High Temp. 49 205-undefined
  • [10] Thakor PB(1961)undefined J. Am. Chem. Soc. 83 4665-undefined