Enantioselective addition of diethyl malonate to ω-nitrostyrenes in the presence of cobalt and manganese complexes with N,N′-dibenzyl-(1S,2S)-cyclohexane-1,2-diamine

被引：0

作者：

A. N. Reznikov

E. V. Golovin

Yu. N. Klimochkin

机构：

[1] Samara State Technical University,

来源：

Russian Journal of General Chemistry | 2012年 / 82卷

关键词：

Diamine; Baclofen; Enantiomeric Excess; Rolipram; Cobalt Complex;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Enantioselective addition of diethyl malonate to nitrostyrene and para-chloronitrostyrene is catalyzed by cobalt and manganese complexes with N,N′-dibenzyl-(1S,2S)-cyclohexane-1,2-diamine generated in situ. Enantiomeric excess of the (R)-isomers in the reaction products is 66–87%.

引用

页码：1827 / 1829

页数：2

共 43 条

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