Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O

被引：0
|
作者：
A. N. Makhinya
M. A. Il’in
I. A. Baidina
I. V. Korol’kov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk National Research State University,undefined
来源：
Journal of Structural Chemistry | 2016年 / 57卷
关键词：
ruthenium; nitroso complexes; ammino complexes; sulfato complexes; chloro complexes; synthesis; single crystal X-ray diffraction analysis; IR spectroscopy;
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摘要：
After the addition of the saturated NaClO4 solution to a solution of trans-[Ru(NO)(NH3)4SO4]HSO4•H2O, trans-[Ru(NO)(NH3)4SO4]ClO4 perchlorate salt (I) is obtained with the yield of ~80%. The heating of trans-[Ru(NO)(NH3)4(H2O)](HSO4)SO4 at a temperature of ~220 °C results in a complete removal of coordination water and a partial removal of ammonia molecules. Successive treatment of the thermolysis product with sulfuric and hydrochloric acids yields [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O crystals (II). The single crystal X-ray diffraction method is used to determine the structure of the compounds obtained. For I: space group P21/c, a = 6.6949(9) Å, b = 13.7049(19) Å, c = 12.8641(17) Å, β = 101.028(4)°; for II: space group Р21/c, a = 14.1304(4) Å, b = 12.4908(3) Å,, c = 11.6264(3) Å, β = 94.1980(10)°.
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页码：1182 / 1187
页数：5
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