Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O

被引：0

作者：

A. N. Makhinya

M. A. Il’in

I. A. Baidina

I. V. Korol’kov

机构：

[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch

[2] Novosibirsk National Research State University,undefined

来源：

Journal of Structural Chemistry | 2016年 / 57卷

关键词：

ruthenium; nitroso complexes; ammino complexes; sulfato complexes; chloro complexes; synthesis; single crystal X-ray diffraction analysis; IR spectroscopy;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

After the addition of the saturated NaClO4 solution to a solution of trans-[Ru(NO)(NH3)4SO4]HSO4•H2O, trans-[Ru(NO)(NH3)4SO4]ClO4 perchlorate salt (I) is obtained with the yield of ~80%. The heating of trans-[Ru(NO)(NH3)4(H2O)](HSO4)SO4 at a temperature of ~220 °C results in a complete removal of coordination water and a partial removal of ammonia molecules. Successive treatment of the thermolysis product with sulfuric and hydrochloric acids yields [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O crystals (II). The single crystal X-ray diffraction method is used to determine the structure of the compounds obtained. For I: space group P21/c, a = 6.6949(9) Å, b = 13.7049(19) Å, c = 12.8641(17) Å, β = 101.028(4)°; for II: space group Р21/c, a = 14.1304(4) Å, b = 12.4908(3) Å,, c = 11.6264(3) Å, β = 94.1980(10)°.

引用

页码：1182 / 1187

页数：5

共 50 条

[1] Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4aEuro¢H2O
Makhinya, A. N.
Il'in, M. A.
Baidina, I. A.
Korol'kov, I. V.
JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 57 (06) : 1182 - 1187
[2] STRUCTURE OF THE FIRST NITROSOAMMINE COMPLEXES OF RUTHENIUM WITH A COORDINATED SULFATE ION: [Ru(NO)(NH3)4(SO4)](HSO4)•H2O AND [Ru(NO)(NH3)3Cl(SO4)]•2H2O
Makhinya, A. N.
Shusharina, E. A.
Baidina, I. A.
Il'in, M. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (05) : 946 - 953
[3] Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O
A. N. Makhinya
M. A. Il’in
I. A. Baidina
P. E. Plyusnin
N. I. Alferova
D. P. Pishchur
Journal of Structural Chemistry, 2014, 55 : 311 - 318
[4] Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3•H2O
Makhinya, A. N.
Il'in, M. A.
Baidina, I. A.
Plyusnin, P. E.
Alferova, N. I.
Pishchur, D. P.
JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (02) : 311 - 318
[5] Structure of the first nitrosoammine complexes of ruthenium with a coordinated sulfate ion: [Ru(NO)(NH3)4(SO 4)](HSO4)·H2O and [Ru(NO)(NH 3)3Cl(SO4)]·2H2O
Makhinya A.N.
Shusharina E.A.
Baidina I.A.
Il'in M.A.
Journal of Structural Chemistry, 2011, 52 (5) : 946 - 953
[6] First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O
M. A. Il’in
V. A. Emel’yanov
I. A. Baidina
Journal of Structural Chemistry, 2010, 51 : 99 - 106
[7] FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O
Il'in, M. A.
Emel'yanov, V. A.
Baidina, I. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 51 (01) : 99 - 106
[8] [Ru(NH3)6](MoO4)Cl·3H2O and [M(NH3)6](ReO4)3·2H2O (M = Ru, Ir). Synthesis and crystal structure
S. P. Khranenko
E. A. Bykova
K. V. Yusenko
A. P. Tyutyunnik
S. A. Gromilov
Journal of Structural Chemistry, 2013, 54 : 931 - 936
[9] [Ru(NH3) 6](MoO4) Cl•3H2O AND [M(NH3)6](ReO4)3•2H2O (M = Ru, Ir). SYNTHESIS AND CRYSTAL STRUCTURE
Khranenko, S. P.
Bykova, E. A.
Yusenko, K. V.
Tyutyunnik, A. P.
Gromilov, S. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (05) : 931 - 936
[10] Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl•H2O
Il'in, M. A.
Emel'yanov, V. A.
Baidina, I. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (06) : 1090 - 1097

← 1 2 3 4 5 →