Thermal decomposition and stability of [Fe(η4-enone)(CO)2L] complexes (L=CO and PPh3)

被引：0

作者：

K. Zutin

V. M. Nogueira

A. E. Mauro

G. R. de Souza

S. I. Klein

机构：

[1] São Paulo State University,Instituto de Química de Araraquara, UNESP

来源：

Journal of Thermal Analysis and Calorimetry | 2007年 / 87卷

关键词：

carbonyliron; enones; thermal analysis; triphenylphosphane;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The compounds [Fe(bda)(CO)2L] and [Fe(ch)(CO)2L], (bda=benzylideneacetone; ch=chalcone; L=CO, PPh3) were investigated by thermogravimetry and derivative thermogravimetry (TG and DTG). The fragmentation patterns suggest that the iron atom protects the enone fragment, so that the organic ligands break up with the loss of the pendant aromatic rings.

引用

页码：449 / 452

页数：3