Herein, we demonstrate the fabrication of highly capacitive activated carbon (AC) using a bio-waste Kusha grass (Desmostachya bipinnata), by employing a chemical process followed by activation through KOH. The as-synthesized few-layered activated carbon has been confirmed through X-ray powder diffraction, transmission electron microscopy, and Raman spectroscopy techniques. The chemical environment of the as-prepared sample has been accessed through FTIR and UV–visible spectroscopy. The surface area and porosity of the as-synthesized material have been accessed through the Brunauer–Emmett–Teller method. All the electrochemical measurements have been performed through cyclic voltammetry and galvanometric charging/discharging (GCD) method, but primarily, we focus on GCD due to the accuracy of the technique. Moreover, the as-synthesized AC material shows a maximum specific capacitance as 218 F g−1 in the potential window ranging from − 0.35 to + 0.45 V. Also, the AC exhibits an excellent energy density of ~ 19.3 Wh kg−1 and power density of ~ 277.92 W kg−1, respectively, in the same operating potential window. It has also shown very good capacitance retention capability even after 5000th cycles. The fabricated supercapacitor shows a good energy density and power density, respectively, and good retention in capacitance at remarkably higher charging/discharging rates with excellent cycling stability. Henceforth, bio-waste Kusha grass-derived activated carbon (DP-AC) shows good promise and can be applied in supercapacitor applications due to its outstanding electrochemical properties. Herein, we envision that our results illustrate a simple and innovative approach to synthesize a bio-waste Kusha grass-derived activated carbon (DP-AC) as an emerging supercapacitor electrode material and widen its practical application in electrochemical energy storage fields.
机构:
CSIR, Electrochem Power Sources ECPS Div, Cent Electrochem Res Inst, Karaikkudi 630003, Tamil Nadu, IndiaCSIR, Electrochem Power Sources ECPS Div, Cent Electrochem Res Inst, Karaikkudi 630003, Tamil Nadu, India
Nadira, Meethale Palakkool
Sathish, Marappan
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CSIR, Electrochem Power Sources ECPS Div, Cent Electrochem Res Inst, Karaikkudi 630003, Tamil Nadu, India
Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, IndiaCSIR, Electrochem Power Sources ECPS Div, Cent Electrochem Res Inst, Karaikkudi 630003, Tamil Nadu, India
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SNU, Sch Chem & Biol Engn, Seoul 08826, South KoreaIncheon Natl Univ, Innovat Ctr Chem Engn, Dept Energy & Chem Engn, 119 Acad Ro, Incheon 22012, South Korea
Kim, Youngkwang
Sung, Yung-Eun
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SNU, Sch Chem & Biol Engn, Seoul 08826, South Korea
Inst for Basic Sci Korea, Ctr Nanoparticle Res, Seoul 08826, South KoreaIncheon Natl Univ, Innovat Ctr Chem Engn, Dept Energy & Chem Engn, 119 Acad Ro, Incheon 22012, South Korea
机构:
State Islamic Univ Sultan Syarif Kasim, Dept Ind Engn, Simpang Baru 28293, Riau, IndonesiaState Islamic Univ Sultan Syarif Kasim, Dept Ind Engn, Simpang Baru 28293, Riau, Indonesia
Taslim, Rika
Halbi, Suryandri
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State Islamic Univ Sultan Syarif Kasim, Dept Ind Engn, Simpang Baru 28293, Riau, IndonesiaState Islamic Univ Sultan Syarif Kasim, Dept Ind Engn, Simpang Baru 28293, Riau, Indonesia
Halbi, Suryandri
Apriwandi, Apriwandi
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Univ Riau, Fac Math & Nat Sci, Dept Phys, Simpang Baru 28293, Riau, IndonesiaState Islamic Univ Sultan Syarif Kasim, Dept Ind Engn, Simpang Baru 28293, Riau, Indonesia