3-Azabicyclo[3.3.1]nonane Derivatives: IV. Synthesis of Amino Acids with 3-Azabicyclo[3.3.1]nonane Fragment

被引：0
|
作者：
I.V. Shakhkel'
E.G. Nikiforova
Yu.D. Grudtsyn
Yu.M. Atroshchenko
O.Ya. Borbulevich
Yu.A. Efremov
S.S. Gitis
D.N. Moiseev
E.N. Alifanova
P.V. Chudakov
A.Yu. Kovalevskii
机构：
[1] Lev Tolstoi Tula State Pedagogical University,Russian Academy of Sciences
[2] Nesmeyanov Institute of Organoelemental Compounds,undefined
来源：
Russian Journal of Organic Chemistry | 2001年 / 37卷
关键词：
Acetic; Potassium; Formaldehyde; Acetic Acid; Organic Chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A series of 1.5-dinitro-3-azabicyclo[3.3.1]non-6-enes was prepared by reduction of 1-R-2,4- and 1-R-3,5-dinitrobenzenes with potassium borohydride followed by Mannich reaction with formaldehyde and amino acids. The molecular structure of (6-bromo-1,5-dinitro-3-azabicyclo[3.3.1]non-6-en-3-yl)acetic acid was studied by X-ray diffraction analysis. The mechanism of decomposition under electron impact was determined for (7-methoxy-1,5-dinitro-3-azabicyclo[3.3.1]non-6-en-3-yl)acetic acid.
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页码：583 / 591
页数：8
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