Electrochemical oxidation of sulfodifluoroacetic acid in the presence of halogens

被引：0

作者：

Smertenko E.A. ^{[1
]}

Volkov N.D. ^{[1
]}

Datsenko S.D. ^{[1
]}

Ignat'ev N.V. ^{[1
]}

机构：

[1] Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev 253094

来源：

Theoretical and Experimental Chemistry | 1999年 / 35卷 / 4期

关键词：

Bromine; Halogen; Anodic Oxidation; Electrochemical Oxidation; Trifluoroacetate;

D O I：

10.1007/BF02511521

中图分类号：

学科分类号：

摘要：

The electrochemical oxidation of sulfodifluoroacetic acid (HOSO2CF2CO2H) in the presence of Cl2 or Br2 gives halodifluoromethanesulfonic acid. The anodic oxidation of sulfodiflitoromethanecarboxylate ion to form the sulfodifluoromethyl radical as an intermediate is proposed as the rate-determining step. © 1999 Kluwer Academic/Plenum Publishers.

引用

页码：231 / 233

页数：2

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