Potential-Barrier Profile for an Adiabatic Electron Transfer Reaction in a Condon Approximation with Allowance for Nonsphericity of Electron Wavefunctions

被引：0
作者：
V. V. Sokolov
A. M. Kuznetsov
机构：
[1] Frumkin Institute of Electrochemistry,Russian Academy of Sciences
来源：
Russian Journal of Electrochemistry | 2002年 / 38卷
关键词：
Physical Chemistry; Electron Transfer; Transfer Reaction; Surface Profile; Activation Barrier;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The free-energy surface profile for an adiabatic electron transfer reaction in a polar solvent is calculated. The calculation allows for the dependence of electron wavefunctions of reactants on the environment polarization and for nonsphericity of electron wavefunctions. Allowance for the nonsphericity reduces significantly the activation barrier and increases the reaction rate.
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页码：1334 / 1338
页数：4
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