Synthesis and crystal structure of tris[2-(N,N-dimethylthiocarbamoyl)benzimidazolato-1]cobalt(III)

被引：0
作者：
A. G. Panasyuk
Z. G. Aliev
A. N. Ranskii
机构：
[1] Dnepropetrovsk Institute of Chemical Technology,Institute of Problems of Chemical Physics
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2006年 / 32卷
关键词：
Physical Chemistry; Crystal Structure; Cobalt; Inorganic Chemistry; Diffraction Analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Conditions for the formation of a CoL3 complex, where L is the deprotonated benzimidazole-2-(N,N-dimethyl)carbothioamide molecule, are studied. The structure of the complex is determined by X-ray diffraction analysis. Each ligand in crystal of the complex is bonded to the metal atom by the bidentate chelate mode at the vertices of a distorted octahedron. The S and N atoms in the octahedron are in the cis-position to each other. All bonds with the same multiplicity in the ligands and in the CoS3N3 octahedron have almost the same length.
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页码：266 / 269
页数：3
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