Hydration numbers of sea water basic ions found by the pulse method of proton NMR

被引：0
|
作者：
N. A. Mel’nichenko
机构：
[1] Far East State University,
来源：
Journal of Structural Chemistry | 2007年 / 48卷
关键词：
sea water; hydration number; relaxation; compressibility;
D O I：
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学科分类号：
摘要：
Hydration numbers of basic ions in sea water (SW) are found from a proton relaxation rate of 1/T1 in SW and model solutions. A possibility for the formation of three-layer hydrate shells around main SW cations and two-layer shells around anions is ascertained. About half of water molecules is in influence zones of ions in sea water that correlates with a double shift in the baric dependence maximum of T1 to a smaller pressure in SW relative to pure water.
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页码：479 / 485
页数：6
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