Electrochemical Polishing of the Surface of a Gold Electrode and Its Effect on the Sensitivity of the Stripping Voltammetric Determination of Mercury(II)

被引：0
|
作者：
S. S. Ermakov
A. V. Borzhitskaya
L. N. Moskvin
机构：
[1] St. Petersburg State University,
来源：
Journal of Analytical Chemistry | 2001年 / 56卷
关键词：
Gold; Ammonium; Analytical Chemistry; Mercury; Detection Limit;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The effect of two different techniques for the preparation of the surface of a gold electrode on the sensitivity of the stripping voltammetric determination of mercury(II) was studied. The electrochemical polishing of the electrode in a solution containing thiourea, sulfuric acid, and ammonium thiocyanate lowered the detection limit for mercury down to 2 ng/L and improved the reproducibility of mercury anodic peaks.
引用
收藏
页码：542 / 545
页数：3
相关论文
共 50 条
  • [31] Cathodic stripping voltammetric determination of ceftazidime in urine at a hanging mercury drop electrode
    Ferreira, VS
    Zanoni, MVB
    Fogg, AG
    MICROCHEMICAL JOURNAL, 1997, 57 (01) : 115 - 122
  • [32] A mercury free electrode for anodic stripping voltammetric determination of Pb (II) ions using poly zincon film modified electrode
    Vasanthi, S.
    Devendiran, M.
    Narayanan, S. Sriman
    APPLIED SURFACE SCIENCE, 2017, 422 : 138 - 146
  • [33] Adsorptive Stripping Voltammetric Determination of Morin in Tea Infusions and Chocolate Drinks on a Gold Electrode. Effect of Cetylpyridinium Bromide on the Sensitivity of the Method
    Arancibia, Veronica
    Gracia-Beltran, Olimpo
    Hurtado, John
    Nagles, Edgar
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2017, 12 (10): : 9408 - 9417
  • [34] SQUARE-WAVE VOLTAMMETRIC STRIPPING ANALYSIS OF MERCURY(II) AT A POLY(4-VINYLPYRIDINE)/GOLD FILM ELECTRODE
    ZEN, JM
    CHUNG, MJ
    ANALYTICAL CHEMISTRY, 1995, 67 (19) : 3571 - 3577
  • [35] Adsorptive Stripping Voltammetric Determination of Cobalt (II) on the Carbon Paste Electrode
    Mohadesi, Alireza
    Teimoori, Elham
    Taher, Mohammad Ali
    Beitollah, Hadis
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2011, 6 (02): : 301 - 308
  • [36] Anodic stripping voltammetric determination of gold on a polyvinylferrocene coated glassy carbon electrode
    Kavanoz, M
    Gülce, H
    Yildiz, A
    TURKISH JOURNAL OF CHEMISTRY, 2004, 28 (03) : 287 - 297
  • [37] Trace determination of mercury by anodic stripping voltammetry at the rotating gold electrode
    Bonfil, Y
    Brand, M
    Kirowa-Eisner, E
    ANALYTICA CHIMICA ACTA, 2000, 424 (01) : 65 - 76
  • [38] Stripping voltammetric and polarographic techniques for the determination of anti-fungal ketoconazole on the mercury electrode
    Arranz, P
    Arranz, A
    Moreda, JM
    Cid, A
    Arranz, JF
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2003, 33 (04) : 589 - 596
  • [39] Adsorptive stripping voltammetric behavior and determination of anticholinergic agent oxybutynin chloride on a mercury electrode
    Jain, Rajeev
    Radhapyari, Keisham
    Jadon, Nimisha
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 314 (02) : 572 - 577
  • [40] Anodic stripping voltammetric determination of thallium(III) using a Tosflex/mercury film electrode
    Lu, TH
    Sun, IW
    ELECTROANALYSIS, 1998, 10 (15) : 1052 - 1056
12345