Acylation of 5-phenyl-2-(fur-2-yl)oxazole

被引:0
作者
Patsenker L.D. [1 ]
Lokshin A.I. [1 ]
Drushlyak T.G. [1 ]
Baumer V.N. [1 ]
机构
[1] Institute of Monocrystals, Academy of Sciences (NAN) of Ukraine
关键词
Organic Chemistry; Transition State; Structure Analysis; Furan; Furan Ring;
D O I
10.1007/BF02320325
中图分类号
学科分类号
摘要
The ability of 5-phenyl-2-(fur-2-yl)oxazole to undergo acetylation and formylation is considered. It was established by x-ray structure analysis that electrophilic substitution proceeds at the position 5 of the furan ring. The direction of the reactions is analyzed from positions of the energy preference of transition states. © 1998 Plenum Publishing Corporation.
引用
收藏
页码:1266 / 1271
页数:5
相关论文
共 12 条
  • [1] Krasovitskii B.M., Bolotin B.M., Organic Luminophores [in Russian], (1984)
  • [2] Katritzky A.R., Schwarz O.A., Rahman A.E.A., Leahy D.E., J. Heterocycl. Chem., 21, (1984)
  • [3] Shershukov V.M., Volkov V.L., Patsenker L.D., Ukr. Rep. Conf. on Organic Chemistry, (1986)
  • [4] Shershukov V.M., Patsenker L.D., Pivnenko N.S., Khim. Geterotsikl. Soedin., 6, (1989)
  • [5] Pozharskii A.F., Theoretical Basis of the Chemistry of Heterocycles [in Russian], (1985)
  • [6] Abronin I.A., Zhidomirov G.M., Khim. Geterotsikl. Soedin., 1, (1977)
  • [7] Pakett L., Basis of the Recent Chemistry of Heterocyclic Compounds [Russian Translation], (1971)
  • [8] Belen'kii L.I., Khim. Geterotsikl. Soedin., 12, (1980)
  • [9] Belen'kii L.I., Gromova G.P., Cheskis M.A., Gol'dfarb Ya.L., Chem. Scr., 25, (1985)
  • [10] Dewar M.J.S., Thiel W., J. Am. Chem. Soc., 99, (1977)