Dispersive liquid-liquid microextraction and solid-phase extraction of polar pesticides from natural water and their determination by micellar electrokinetic chromatography

Procedures for the determination of polar pesticides in surface and ground water after their preconcentration by dispersive liquid-liquid microextraction and solid-phase extraction on Oasis® HLB (3 cc/60 mg) extraction cartridges are proposed. Conditions for the separation and determination of pesticides from the following classes by micellar electrokinetic chromatography were chosen: arylhydroxycarboxylic acids, sym-triazines, triazinones, urea derivatives, neonicotinoids, carbamates, triazoles, imidazoles, benzimidazoles, and organophosphorus compounds. The determination limits of pesticides in water were 0.5–20 μg/L with consideration for preconcentration. The relative standard deviation of the results of analysis was no higher than 10%.