fac-Re(bpy)(CO)3(COOMe): A model metallocarboxylate complex of rhenium with a bipyridyl ligand

被引：0

作者：

Dorothy H. Gibson

Bradley A. Sleadd

Ashwani Vij

机构：

[1] University of Louisville,Department of Chemistry and Center for Chemical Catalysis

[2] University of Idaho,Department of Chemistry

来源：

Journal of Chemical Crystallography | 1999年 / 29卷

关键词：

metallocarboxylate ester; rhenium complex; 2,2′-bipyridyl ligand;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The title compound, fac-(2,2′-bipyridyl)(carbomethoxy)rhenium tricarbonyl, crystallizes in the monoclinic system, space group P21/c with the following crystal data: a = 8.37551(1), b = 6.6934(1), c = 26.2098(1) Å, V(Å3) = 1535.93(3), Z = 4, and β = 90.0971(2). The metal environment is slightly distorted octahedral with a chelating bipyridyl ligand and a facial arrangement of the carbon monoxide ligands.

引用

页码：619 / 622

页数：3

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