New synthetic methods of π-conjugated inclusion complexes with high conductivity

被引：1
作者：
Jun Terao
Yasushi Tsuji
机构：
[1] Kyoto University,Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering
来源：
Journal of Inclusion Phenomena and Macrocyclic Chemistry | 2014年 / 80卷
关键词：
π-Conjugated molecular wire; Molecular electronics; Functionalized molecular wire; Cyclodextrin; Poly(phenylene ethynylene); Rotaxane; [1]Rotaxane; Polyrotaxane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new method for the synthesis of an insulated π-conjugated molecule was developed via the sequential self-inclusion of π-conjugated guest branched permethylated α-cyclodextrin followed by the elongation of the π-conjugated unit. Covering a single π-conjugated wire by an α-cyclodextrin derivatives can suppress conductance fluctuation. The insulated π-conjugated molecules were utilized in the synthesis of highly conductive zigzag- and functionalized-insulated molecular wires.
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页码：165 / 175
页数：10
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