Recovery of plutonium from uranium analytical waste solution containing phosphate using 2-ethylhexyl 2-ethylhexyl phosphonic acid (PC88A)

被引:0
|
作者
K. Venugopal Chetty
Jayashree S. Gamare
A. G. Godbole
V. N. Vaidya
机构
[1] Fuel Chemistry Division,
[2] Bhabha Atomic Research Centre,undefined
[3] Fuel Chemistry Division,undefined
[4] Bhabha Atomic Research Centre,undefined
[5] Fuel Chemistry Division,undefined
[6] Bhabha Atomic Research Centre,undefined
[7] Fuel Chemistry Division,undefined
[8] Bhabha Atomic Research Centre,undefined
来源
Journal of Radioanalytical and Nuclear Chemistry | 2006年 / 269卷
关键词
Plutonium; Dodecane; HDEHP; Waste Solution; Loaded Organic Phase;
D O I
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摘要
The isolation of plutonium from simulated uranium analytical waste solution was studied using 2-ethylhexyl 2-ethylhexyl phosphonic acid (PC88A) in dodecane. The batch distribution data obtained from aqueous phase containing sulphuric, nitric and phosphoric acids showed that further addition of nitric acid results in higher distribution values for plutonium(IV). In the present study plutonium was recovered from several litres of the waste solution without adding any acid using PC88A. The plutonium extracted into the organic phase was stripped using 1M oxalic acid containing 0.2M ascorbic acid.
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页码:15 / 20
页数:5
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