X-ray diffraction study of ion thermal vibrations in R2CuO4 (R=Pr and Gd) crystals

被引:0
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作者
A. A. Levin
Yu. I. Smolin
Yu. F. Shepelev
E. I. Golovenchits
V. A. Sanina
机构
[1] Russian Academy of Sciences,Grebenshchikov Institute of Silicate Chemistry
[2] Russian Academy of Sciences,Ioffe Physicotechnical Institute
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关键词
Spectroscopy; Phase Transition; State Physics; Spatial Distribution; Structural Phase;
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摘要
An X-ray diffraction study is reported of the symmetry in the spatial distribution of thermal vibrations of Cu2+, Gd3+, and Pr3+ ions in Gd2CuO4 crystals. An analysis of the pattern of the angular thermal-vibration amplitude distribution obtained experimentally at different temperatures allows a conclusion about the character of the local Jahn-Teller effect for the Cu2+ ions, structural phase transitions, and the orbital ground state of the Cu2+ ions.
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页码:153 / 160
页数:7
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