Some composite materials, such as Zirconia-toughened ceramics, are remarkable materials which have high strength, a high elastic modulus, and an improved toughness, etc. These good qualities are made possible through the stress-induced phase transformation of composite particles, which is accompanied by an impact cooling. When a spherical inclusion in an infinite elastic domain is suddenly subjected to an instantaneous phase transformation, stress waves occur at the surface of a spherical inclusion at the moment thermal impact is applied. The wave may accumulate at the center and show stress-focusing effects, even though the initial stress may be relatively small. This paper analyzes the thermal stress-focusing effect caused by the instantaneous anisotropic phase transformations in the spherical Zirconia inclusion. By use of ray theory, the numerical results give a clear indication of the mechanism of stress-focusing in an inclusion embedded in an infinite elastic medium.