Manganese-Catalyzed Carbomagnesation of Alkynes

被引：1

作者：

Hiroshi Shinokubo

Koichiro Oshima

机构：

[1] Kyoto University,Department of Material Chemistry, Graduate School of Engineering

来源：

Catalysis Surveys from Asia | 2003年 / 7卷

关键词：

manganese; alkyne; Grignard reagent; carbometallation; cyclization;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The development of manganese-catalyzed carbomagnesation of alkynes is reviewed. Manganese salts mediate the efficient addition of a variety of Grignard reagents to alkynes. Allyl, aryl, and alkyl Grignard reagents participate in these reactions. In many cases, a hetero atom such as oxygen or nitrogen in substrates facilitates the addition reaction. Stoichiometric carbometalation reactions with manganese ate complexes are also discussed, as is cyclization of 1,6-diynes and 1,6-enynes via carbometalation with triallylmanganate.

引用

页码：39 / 46

页数：7