Host-guest complexation of cucurbit[8]uril with two enantiomers

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作者
Zhong-Zheng Gao
Rui-Lian Lin
Dong Bai
Zhu Tao
Jing-Xin Liu
Xin Xiao
机构
[1] Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province,
[2] Guizhou University,undefined
[3] College of Chemistry and Chemical Engineering,undefined
[4] Anhui University of Technology,undefined
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Scientific Reports | / 7卷
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摘要
Host-guest complexation of cucurbit[8]uril (Q[8]) with two enantiomers, D-3-(2-naphthyl)-alanine (D-NA) and L-3-(2-naphthyl)-alanine (L-NA), has been fully investigated. Experimental data indicate that double guests reside within the cavity of Q[8] in both aqueous solution and solid state, generating highly stable homoternary complexes D-NA2@Q[8] and L-NA2@Q[8].
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