Crystal structure and magnetic properties of a three-dimensional complex constructed from [CuL]2+ and [Fe(CN)6]3− precursors

被引：0
作者：
Ai-hua Yuan
Xiao-ping Shen
Hu Zhou
机构：
[1] Jiangsu University of Science and Technology,School of Material Science and Engineering
[2] Jiangsu University,School of Chemistry and Chemical Engineering
来源：
Transition Metal Chemistry | 2008年 / 33卷
关键词：
Prussian Blue; Teller Effect; Ferromagnetic Interaction; Prussian Blue Analogue; Octahedral Coordination Environment;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Self-assembly of the precursor [Cu(L)]2+ (L = 3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane) with hexacyanometalate [Fe(CN)6]3− produces a 3-D cyano-bridged Cu(II)–Fe(III) bimetallic assembly, [CuL]2[Fe(CN)6]ClO4 · H2O (1), characterized by single-crystal X-ray diffraction studies, and magnetic measurements. The crystallographic determination reveals that each hexacyanoferromate(III) ion connects four copper(II) ions using four co-planar CN− groups which axially coordinate to the copper ion in a trans fashion forming trans-CuL(N≡C)2 moieties in (1). Magnetic studies reveal that (1) displays a ferromagnetic interaction between Cu(II) and Fe(III) through the CN linkage.
引用
收藏
页码：133 / 136
页数：3
相关论文
共 12 条
  • [1] THE 2-DIMENSIONAL NETWORK STRUCTURE AND METAMAGNETIC PROPERTIES OF THE 2/1 COMPLEX OF [MN(3-MEOSALEN)(H2O)]CLO4 AND K-3[FE(CN)(6)]
    MIYASAKA, H
    MATSUMOTO, N
    OKAWA, H
    RE, N
    GALLO, E
    FLORIANI, C
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14): : 1446 - 1448
  • [2] Synthesis and crystal structure of a cyanide-bridged one-dimensional nickel(II) complex with alternating [Ni(En)2]2+ and [Ni(CN)4]2− ions
    B. Tao
    H. Xia
    X. Jiang
    Y. F. Zhu
    Russian Journal of Coordination Chemistry, 2011, 37 : 367 - 370
  • [3] Synthesis, crystal structure and magnetic properties of a new three-dimensional porous framework:: [Gd2(BDA)3(DMF)2(H2O)4] • 2DMF
    Wu, Chuan-De
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (12) : 1223 - 1226
  • [4] Heat-induced magnetic properties changes of Mn3[Fe(CN)6]2•xH2O
    Liu, Min
    Xu, Mingxiang
    PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 9, NO 1, 2012, 9 (01): : 89 - 92
  • [5] [Mn(C4H10ON)(H2O)][Fe(CN)6]: A Three-Dimensional Cyanide-Bridged Ferrimagnet with a Morpholine Ligand
    Jiang, Ning
    Li, Feng-Yan
    Xu, Lin
    Zhao, Li-Li
    Wang, Yu-Chao
    INORGANIC CHEMISTRY, 2011, 50 (04) : 1544 - 1550
  • [6] Synthesis, crystal structure and magnetic property of one-dimensional heterometallic cyanide-bridged complex: {[Cu(hmpH)2Cu(hmp)(hmpH) Co(μ,-CN)4(CN)2].2H2O}n
    Sayin, Elvan
    Kurkcuoglu, Gunes Suheyla
    Yesilel, Okan Zafer
    Tas, Murat
    Ozturk, Mustafa
    Yerli, Yusuf
    POLYHEDRON, 2016, 115 : 67 - 75
  • [7] Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]3[Fe(CN)6]2•8H2O (L=6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)
    Cha, Min Ju
    Shin, Jong Won
    Lee, Young Hoon
    Kim, Yang
    Kim, Bong Gon
    Min, Kil Sik
    INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (06) : 520 - 522
  • [8] Three-dimensional bimetallic ferrimagnets [Mn(L)]3[Cr(CN)6]2 • nH2O (L = ethylenediamine, n=4; L = glycine amide, n=2.5) and relevance to a Prussian Blue analogue Mn3[Cr(CN)6]2 • 12H2O
    Usuki, N
    Yamada, M
    Ohba, M
    Okawa, H
    JOURNAL OF SOLID STATE CHEMISTRY, 2001, 159 (02) : 328 - 335
  • [9] Magnetic properties of nanoparticles of Prussian blue-based molecular magnets M3[Cr(CN)6]2⋅zH2O (M=Fe, Co, and Ni)
    Pramod Bhatt
    S. M. Yusuf
    Ranu Bhatt
    G. Schütz
    Applied Physics A, 2012, 109 : 459 - 469
  • [10] The crystal structure of the hydrated cyano complexes NMe4MnII[(Mn, Cr)III(CN)6] • 3 H2O and NMe4Cd[MIII(CN)6] • 3 H2O (MIII = Fe, Co):: Compounds related to Prussian Blue
    Witzel, M
    Ziegler, B
    Babel, D
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (02): : 471 - 477
12