Effect of different plasticizer on structural and electrical properties of PEMA-based polymer electrolytes

被引:0
作者
S. Rajendran
M. Ramesh Prabhu
机构
[1] Alagappa University,School of Physics
来源
Journal of Applied Electrochemistry | 2010年 / 40卷
关键词
Polymer blends; Plasticization; Complex impedance spectroscopy; XRD; Dielectric relaxation;
D O I
暂无
中图分类号
学科分类号
摘要
Plasticized poly(vinyl chloride)/poly(ethyl methacrylate) PVC/PEMA-based blend polymer electrolyte films containing lithium perchlorate (LiClO4) as a salt were prepared by solvent casting technique. The effects of the plasticization on structural, thermal and electrical properties of the plasticized polymer blend electrolytes were investigated. The changes in the structural and complex formation properties of the materials were studied by XRD and FTIR techniques. Dielectric relaxation studies of the polymer electrolyte have been undertaken, and the results are discussed. TG/DTA technique is used to study the thermal stability. Complex impedance analysis is used to calculate the bulk resistance of the complexes. The effect of different plasticizer on the structural and physical properties of polymer blend electrolyte is well correlated.
引用
收藏
页码:327 / 332
页数:5
相关论文
共 50 条
  • [41] Effect of K+ ion doping on structural and physical properties of PVA/MAA:EA polymer blend electrolytes
    Tellamekala S.
    Ojha P.
    N.O G.
    Nagabhushana H.
    Ch R.
    Materials Research Innovations, 2020, : 1 - 13
  • [42] Effect of different etching times on the structural, morphological, electrical, and antimicrobial properties of mesoporous silicon
    Sivaprakash, P.
    Venkatesan, Raja
    Muthu, S. Esakki
    Hatshan, Mohammad Rafe
    Vetcher, Alexandre A.
    Kim, Seong-Cheol
    Kim, Ikhyun
    HELIYON, 2023, 9 (12)
  • [43] Effect of plasticizer on electrical conductivity and cell parameters of (PVC+KBrO3)polymer electrolyte system
    Reddy, T. Janaki Rami
    Achari, V. B. S.
    Sharma, A. K.
    Rao, V. V. R. Narasimha
    IONICS, 2007, 13 (01) : 55 - 59
  • [44] Effect of ethylene carbonate concentration on structural and electrical properties of PEO-PMMA polymer blends
    Sharma, Poonam
    Kanchan, D. K.
    Gondaliya, Nirali
    IONICS, 2013, 19 (05) : 777 - 785
  • [45] Effect of plasticizer on electrical conductivity and cell parameters of (PVC+KBrO3) polymer electrolyte system
    T. Janaki Rami Reddy
    V. B. S. Achari
    A. K. Sharma
    V. V. R. Narasimha Rao
    Ionics, 2007, 13 : 55 - 59
  • [46] Enhanced electrical and electrochemical properties of PMMA-clay nanocomposite gel polymer electrolytes
    Deka, M.
    Kumar, A.
    ELECTROCHIMICA ACTA, 2010, 55 (05) : 1836 - 1842
  • [47] Microstructure, electrical, and transport properties: Graphene oxide reinforced poly (vinyl alcohol)-chitosan based polymer blend electrolytes
    Sagar, Rohan N.
    Ravindrachary, V.
    Hegde, Shreedatta
    MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2025, 317
  • [48] Electrical and electrochemical studies on magnesium ion-based polymer gel electrolytes
    Tripathi, S. K.
    Jain, Amrita
    Gupta, Ashish
    Mishra, Manju
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (05) : 1799 - 1806
  • [49] Effect of PVA Blending on Structural and Ion Transport Properties of CS:AgNt-Based Polymer Electrolyte Membrane
    Aziz, Shujahadeen B.
    Abdullah, Omed Gh.
    Hussein, Sarkawt A.
    Ahmed, Hameed M.
    POLYMERS, 2017, 9 (11):
  • [50] Structural and Electrical Characterization of Hexanoyl Chitosan-LiClO4-TiO2-DMC Polymer Electrolytes
    Muhammad, F. H.
    Subban, R. H. Y.
    Winie, Tan
    ADVANCED MATERIALS ENGINEERING AND TECHNOLOGY II, 2014, 594-595 : 608 - +